Formation of a Ph2PCH(BH3)P(BH3)Ph2 ligand via formal 1,2-borane migration

Jens Langer; Villö K. Pálfi; Helmar Görls; Markus Reiher; Matthias Westerhausen

doi:10.1039/C2CC38098F

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Formation of a Ph₂PCH(BH₃)P(BH₃)Ph₂ligandvia formal 1,2-borane migration†

Jens Langer,*^a Villö K. Pálfi,^b Helmar Görls,^a Markus Reiher^b and Matthias Westerhausen^a

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* Corresponding authors

^a Institute of Inorganic and Analytical Chemistry, Friedrich-Schiller-University Jena, Humboldtstraße 8, D-07743 Jena, Germany
E-mail: j.langer@uni-jena.de
Fax: +49 3641 948132
Tel: +49 3641 948126

^b Laboratorium für Physikalische Chemie, ETH Zürich, Wolfgang-Pauli-Str. 10, CH-8093 Zürich, Switzerland
E-mail: markus.reiher@phys.chem.ethz.ch
Fax: +41 44 633 15
Tel: +41 44 633 43 08

Abstract

The transfer of the anionic Ph₂P(BH₃)–CH–P(BH₃)Ph₂ ligand from potassium to barium results in the subsequent formation of a tetranuclear barium cluster which contains the hitherto unknown isomeric form Ph₂P–CH(BH₃)–P(BH₃)Ph₂ of the ligand.

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Article information

DOI: https://doi.org/10.1039/C2CC38098F
Article type: Communication
Submitted: 18 Oct 2012
Accepted: 30 Nov 2012
First published: 06 Dec 2012

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Chem. Commun., 2013,49, 1121-1123

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Formation of a Ph₂PCH(BH₃)P(BH₃)Ph₂ ligand via formal 1,2-borane migration

J. Langer, V. K. Pálfi, H. Görls, M. Reiher and M. Westerhausen, Chem. Commun., 2013, 49, 1121 DOI: 10.1039/C2CC38098F

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