Issue 19, 2013
From the journal:

Chemical Communications

Directed nucleation of monomeric and dimeric uranium(vi) complexes with a room temperature carboxyl-functionalized phosphonium ionic liquid†

Xiao-Yan Chen,a   George S. Goff,*a   Mauricio Quiroz-Guzman,b   Daniel P. Fagnant, Jr.,b   Joan F. Brennecke,b   Brian L. Scottc  and  Wolfgang Runde*d  

* Corresponding authors

a Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA
E-mail: georgeg@lanl.gov

b Department of Chemical and Biomolecular Engineering, University of Notre Dame, 182 Fitzpatrick Hall, Notre Dame, IN 46556, USA

c Material Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

d Science Program Office, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA
E-mail: runde@lanl.gov

Abstract

The carboxyl-functionalized phosphonium ionic liquid (IL), [HCTMP][Tf2N], enabled the directed nucleation of monomeric or dimeric uranyl(VI) compounds. This new IL is the first carboxyl-functionalized IL which is liquid at room temperature and exhibits a wider electrochemical window and lower melting point than its ammonium analogue.

Graphical abstract: Directed nucleation of monomeric and dimeric uranium(vi) complexes with a room temperature carboxyl-functionalized phosphonium ionic liquid

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Article information

DOI
https://doi.org/10.1039/C2CC38255E
Article type
Communication
Submitted
15 Nov 2012
Accepted
12 Dec 2012
First published
08 Jan 2013

Chem. Commun., 2013,49, 1903-1905

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Directed nucleation of monomeric and dimeric uranium(VI) complexes with a room temperature carboxyl-functionalized phosphonium ionic liquid

X. Chen, G. S. Goff, M. Quiroz-Guzman, D. P. Fagnant, J. F. Brennecke, B. L. Scott and W. Runde, Chem. Commun., 2013, 49, 1903 DOI: 10.1039/C2CC38255E

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