A catalytic intermolecular carbon electrophile induced semipinacol rearrangement was realized and the asymmetric version was also preliminarily accomplished with 92% and 82% ee. The complex tricyclic system architecture with four continuous stereogenic centers could be achieved from simple starting materials in a single step under mild conditions.
Q. Zhang, X. Zhang, B. Li, K. Xiang, F. Zhang, S. Wang and Y. Tu, Chem. Commun., 2013, 49, 1648 DOI: 10.1039/C2CC38585F
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