Issue 34, 2013

Organic multishell isostructural host–guest crystals: fullerenes C60 inside a nitroxide open framework

Abstract

The dinitroxide biradical bTbk crystallizes forming hexagonal open frameworks with one-dimensional corrugated channels filled with crystallization solvent. The large pockets constitutive of the channels allowed the inclusion of C60 in the paramagnetic network. The rapidity and high fidelity of crystal growth were used to prepare isostructural multilayer host–guest crystals successively stained with C60.

Graphical abstract: Organic multishell isostructural host–guest crystals: fullerenes C60 inside a nitroxide open framework

Supplementary files

Article information

Article type
Communication
Submitted
08 Jan 2013
Accepted
07 Mar 2013
First published
07 Mar 2013

Chem. Commun., 2013,49, 3519-3521

Organic multishell isostructural host–guest crystals: fullerenes C60 inside a nitroxide open framework

D. Bardelang, M. Giorgi, C. Pardanaud, V. Hornebecq, E. Rizzato, P. Tordo and O. Ouari, Chem. Commun., 2013, 49, 3519 DOI: 10.1039/C3CC00170A

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