Issue 17, 2013
From the journal:

Chemical Communications

Iodine-catalyzed tandem synthesis of terminal acetals and glycol mono esters from olefins†

Macharla Arun Kumar,a   Peraka Swamy,a   Mameda Naresh,a   Marri Mahender Reddy,a   Chozhiyath Nappunni Rohitha,a   Sripadi Prabhakar,b   Akella Venkata Subrahmanya Sarma,c   Joseph Richard Prem Kumard  and  Nama Narender*a  

* Corresponding authors

a I&PC Division, CSIR-IICT, Hyderabad 500 007, India
E-mail: narendern33@yahoo.co.in

b NCMS, CSIR-IICT, Hyderabad 500 007, India

c Centre for NMR, CSIR-IICT, Hyderabad 500 007, India

d CMM, CSIR-IICT, Hyderabad 500 007, India

Abstract

A new metal-free protocol is described for the synthesis of terminal acetals by tandem oxidative rearrangement of olefins using oxone as an oxidant in the presence of iodine. Moreover, a one-pot procedure for the preparation of glycol mono esters from olefins is also presented for the first time using the same reagent system.

Graphical abstract: Iodine-catalyzed tandem synthesis of terminal acetals and glycol mono esters from olefins

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC38085H
Article type
Communication
Submitted
08 Nov 2012
Accepted
09 Jan 2013
First published
11 Jan 2013

Chem. Commun., 2013,49, 1711-1713

Permissions

Request permissions

Iodine-catalyzed tandem synthesis of terminal acetals and glycol mono esters from olefins

M. A. Kumar, P. Swamy, M. Naresh, M. M. Reddy, C. N. Rohitha, S. Prabhakar, A. V. S. Sarma, J. R. P. Kumar and N. Narender, Chem. Commun., 2013, 49, 1711 DOI: 10.1039/C3CC38085H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements