Issue 16, 2013
From the journal:

Chemical Communications

A charge-polarized porous metal–organic framework for gas chromatographic separation of alcohols from water†

Jian-Ke Sun,a   Min Ji,*b   Cheng Chen,a   Wu-Gen Wang,b   Peng Wang,a   Rui-Ping Chena  and  Jie Zhang*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian, P. R. China
E-mail: zhangjie@fjirsm.ac.cn
Fax: +86 591-83710051

b School of Chemistry, Dalian University of Technology, Dalian 116024, Liaoning, P. R. China
E-mail: jimin@dlut.edu.cn

Abstract

A bipyridinium ligand with a charge separated skeleton has been introduced into a metal–organic framework to yield a porous material with charge-polarized pore space, which exhibits selective adsorption for polar guest molecules and can be further used in gas chromatography for the separation of alcohol–water mixtures.

Graphical abstract: A charge-polarized porous metal–organic framework for gas chromatographic separation of alcohols from water

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Article information

DOI
https://doi.org/10.1039/C3CC38260E
Article type
Communication
Submitted
16 Nov 2012
Accepted
08 Jan 2013
First published
08 Jan 2013

Chem. Commun., 2013,49, 1624-1626

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A charge-polarized porous metal–organic framework for gas chromatographic separation of alcohols from water

J. Sun, M. Ji, C. Chen, W. Wang, P. Wang, R. Chen and J. Zhang, Chem. Commun., 2013, 49, 1624 DOI: 10.1039/C3CC38260E

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