Issue 26, 2013
From the journal:

Chemical Communications

One-pot synthesis of benzamide over a robust tandem catalyst based on center radially fibrous silica encapsulated TS-1†

Hong-gen Peng,a   Le Xu,a   Haihong Wu,a   Kun Zhanga  and  Peng Wu*a  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, North Zhongshan Road 3663, Shanghai 200062, China
E-mail: pwu@chem.ecnu.edu.cn
Fax: +86-21 62232292

Abstract

A center radially fibrous silica encapsulated TS-1 zeolite (TS-1@KCC-1) has been synthesized in a microemulsion system for the first time. Supporting the Rh(OH)3 species, this novel core–shell structured material serves as a robust bifunctional catalyst for one-pot synthesis of benzamide from benzaldehyde, ammonia and hydrogen peroxide, in which the aldehyde ammoximation and oxime rearrangement occur in a tandem way.

Graphical abstract: One-pot synthesis of benzamide over a robust tandem catalyst based on center radially fibrous silica encapsulated TS-1

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Article information

DOI
https://doi.org/10.1039/C3CC38546A
Article type
Communication
Submitted
28 Nov 2012
Accepted
07 Feb 2013
First published
08 Feb 2013

Chem. Commun., 2013,49, 2709-2711

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One-pot synthesis of benzamide over a robust tandem catalyst based on center radially fibrous silica encapsulated TS-1

H. Peng, L. Xu, H. Wu, K. Zhang and P. Wu, Chem. Commun., 2013, 49, 2709 DOI: 10.1039/C3CC38546A

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