Issue 27, 2013
From the journal:

Chemical Communications

Synthesis of a bicyclic diborane by selective boron carbon bond formation†

Holger Braunschweig,*a   Alexander Dammea  and  Thomas Kupfera  

* Corresponding authors

a Institut für Anorganische Chemie, Julius-Maximilians-Universität, Würzburg, Am Hubland, D-97074 Würzburg, Germany
E-mail: h.braunschweig@uni-wuerzburg.de
Fax: +49 931 31 84623
Tel: +49 931 31 85260

Abstract

The bicyclic diboron species 1 was generated with high selectivity by a combination of boron carbon bond formation and hydrogen iodide elimination events. The nature of the boracycle 1 was evaluated using X-ray diffraction, NMR spectroscopy and density functional theory calculations.

Graphical abstract: Synthesis of a bicyclic diborane by selective boron carbon bond formation

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Article information

DOI
https://doi.org/10.1039/C3CC38789E
Article type
Communication
Submitted
07 Dec 2012
Accepted
14 Feb 2013
First published
18 Feb 2013

Chem. Commun., 2013,49, 2774-2776

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Synthesis of a bicyclic diborane by selective boron carbon bond formation

H. Braunschweig, A. Damme and T. Kupfer, Chem. Commun., 2013, 49, 2774 DOI: 10.1039/C3CC38789E

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