Issue 30, 2013
From the journal:

Chemical Communications

Lanthanide corroles: a new class of macrocyclic lanthanide complexes†

Heather L. Buckley,a   Mitchell R. Anstey,*b   Daniel T. Grykocd  and  John Arnold*a  

* Corresponding authors

a Department of Chemistry, University of California, Berkeley, California, USA
E-mail: arnold@berkeley.edu
Tel: 001 510 643 5181

b Sandia National Laboratories, Livermore, California, USA
E-mail: mantsey@sandia.gov

c Institute for Organic Chemistry, Polish Academy of Sciences, Warsaw, Poland
E-mail: dtgryko@icho.edu.pl
Tel: +48 22 3433063

d Warsaw University of Technology, Faculty of Chemistry, Warsaw, Poland

Abstract

The first examples of lanthanide corroles are prepared by two synthetic routes. (Mes2(p-OMePh)corrole)La·4.5DME (1·4.5DME) and (Mes2(p-OMePh)corrole)Tb·4DME (2·4DME) are prepared from the free base corrole and Ln((NSiMe3)2)3, while (Mes2(p-OMePh)corrole)Gd·TACNMe3 (3·TACNMe3) is prepared by metathesis of the recently reported Li3 corrole and GdCl3.

Graphical abstract: Lanthanide corroles: a new class of macrocyclic lanthanide complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC38806A
Article type
Communication
Submitted
08 Dec 2012
Accepted
26 Feb 2013
First published
28 Feb 2013

Chem. Commun., 2013,49, 3104-3106

Permissions

Request permissions

Lanthanide corroles: a new class of macrocyclic lanthanide complexes

H. L. Buckley, M. R. Anstey, D. T. Gryko and J. Arnold, Chem. Commun., 2013, 49, 3104 DOI: 10.1039/C3CC38806A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements