Issue 22, 2013
From the journal:

Chemical Communications

P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes†

Tianshu Li,a   Michael T. Gamer,a   Manfred Scheer,b   Sergey N. Konchenko*ac  and  Peter W. Roesky*a  

* Corresponding authors

a Institut für Anorganische Chemie, Karlsruher Institut für Technologie (KIT), Engesserstr. 15, Geb. 30.45, 76131 Karlsruhe, Germany
E-mail: roesky@kit.edu

b Institut für Anorganische Chemie der Universität Regensburg, 93040 Regensburg, Germany

c Nikolaev Institute of Inorganic Chemistry SB RAS, Prosp. Lavrentieva 3, 630090 Novosibirsk, Russia

Abstract

The two new 3d/4f polyphosphide complexes [(Cp*Fe)2P10{Sm(η5-C5Me4R)2}2] (Cp* = η5-C5Me5; R = Me, nPr) were prepared by reductive dimerization of [Cp*Fe(η5-P5)] with samarocenes. They are the first P10 bridging 3d/4f metal complexes and the first examples of reductive coupling of polyphosphide complexes by divalent lanthanides.

Graphical abstract: P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes

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Article information

DOI
https://doi.org/10.1039/C3CC38841G
Article type
Communication
Submitted
10 Dec 2012
Accepted
18 Jan 2013
First published
05 Feb 2013

Chem. Commun., 2013,49, 2183-2185

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P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes

T. Li, M. T. Gamer, M. Scheer, S. N. Konchenko and P. W. Roesky, Chem. Commun., 2013, 49, 2183 DOI: 10.1039/C3CC38841G

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