A polyoxometalate-based single-molecule magnet with a mixed-valent {MnIV2MnIII6MnII4} core

Zhi-Ming Zhang; Shuang Yao; Yang-Guang Li; Hai-Hong Wu; Yong-Hui Wang; Mathieu Rouzières; Rodolphe Clérac; Zhong-Min Su; En-Bo Wang

doi:10.1039/C3CC38981B

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A polyoxometalate-based single-molecule magnet with a mixed-valent {Mn^IV₂Mn^III₆Mn^II₄} core†

Zhi-Ming Zhang,^a Shuang Yao,^b Yang-Guang Li,*^a Hai-Hong Wu,^a Yong-Hui Wang,^a Mathieu Rouzières,^cd Rodolphe Clérac,*^cd Zhong-Min Su^a and En-Bo Wang*^a

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* Corresponding authors

^a Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Ren Min Street No. 5268, Changchun, Jilin 130024, P. R. China
E-mail: liyg658@nenu.edu.cn, wangeb889@nenu.edu.cn

^b College of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun, Jilin, P. R. China

^c CNRS, CRPP, UPR 8641, Research team for “Molecular Magnetic Materials”, F-33600 Pessac, France
E-mail: clerac@crpp-bordeaux.cnrs.fr

^d Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France

Abstract

A polyoxometalate (POM)-based {Mn^IV₂Mn^III₆Mn^II₄} complex with single-molecule magnet (SMM) behaviour was prepared, exhibiting the largest known Mn nuclearity and the most Mn valence states in the POM-based SMM family.

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Article information

DOI: https://doi.org/10.1039/C3CC38981B
Article type: Communication
Submitted: 16 Dec 2012
Accepted: 05 Feb 2013
First published: 06 Feb 2013

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Chem. Commun., 2013,49, 2515-2517

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A polyoxometalate-based single-molecule magnet with a mixed-valent {Mn^IV₂Mn^III₆Mn^II₄} core

Z. Zhang, S. Yao, Y. Li, H. Wu, Y. Wang, M. Rouzières, R. Clérac, Z. Su and E. Wang, Chem. Commun., 2013, 49, 2515 DOI: 10.1039/C3CC38981B

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