Issue 30, 2013

Equilibrium between Fe(iv) porphyrin and Fe(iii) porphyrin radical cation: new insight into the electronic structure of high-valent iron porphyrin complexes

Abstract

UV-Vis, NMR, and Mössbauer studies have revealed that [Fe(TMP)(N3)2], showing the Mössbauer parameters quite similar to those of the ferryl species of MauG, CytP450BM3, Cyt P450CAM, and CPO, exists as equilibrium mixtures of Fe(IV) porphyrin and Fe(III) porphyrin radical cation.

Graphical abstract: Equilibrium between Fe(iv) porphyrin and Fe(iii) porphyrin radical cation: new insight into the electronic structure of high-valent iron porphyrin complexes

Supplementary files

Article information

Article type
Communication
Submitted
14 Jan 2013
Accepted
11 Feb 2013
First published
12 Feb 2013

Chem. Commun., 2013,49, 3098-3100

Equilibrium between Fe(IV) porphyrin and Fe(III) porphyrin radical cation: new insight into the electronic structure of high-valent iron porphyrin complexes

A. Ikezaki, M. Takahashi and M. Nakamura, Chem. Commun., 2013, 49, 3098 DOI: 10.1039/C3CC40319J

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