Issue 50, 2013
From the journal:

Chemical Communications

Palladium-catalyzed asymmetric coupling cyclization of terminal γ-allenols with aryl iodides†

Xi Xiea  and  Shengming Ma*ab  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062, P. R. China
E-mail: masm@sioc.ac.cn
Fax: +86-21-6260-9305

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, P. R. China

Abstract

A Pd-catalyzed asymmetric coupling cyclization of γ-allenols has been developed. Styrenyl derivatives can be prepared in 60–86% yields with ee values ranging from 85–92%.

Graphical abstract: Palladium-catalyzed asymmetric coupling cyclization of terminal γ-allenols with aryl iodides

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Article information

DOI
https://doi.org/10.1039/C3CC40892B
Article type
Communication
Submitted
02 Feb 2013
Accepted
14 Apr 2013
First published
15 Apr 2013

Chem. Commun., 2013,49, 5693-5695

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Palladium-catalyzed asymmetric coupling cyclization of terminal γ-allenols with aryl iodides

X. Xie and S. Ma, Chem. Commun., 2013, 49, 5693 DOI: 10.1039/C3CC40892B

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