Issue 44, 2013

Nickel-catalyzed [3 + 2] cycloaddition of diynes with methyleneaziridines via C–C bond cleavage

Abstract

A Ni-catalyzed [3 + 2] cycloaddition via C–C bond cleavage of methyleneaziridines under mild conditions was developed. This reaction gave substituted pyrroles with excellent regioselectivity and a pendant alkyne unit, which is advantageous for further derivatization.

Graphical abstract: Nickel-catalyzed [3 + 2] cycloaddition of diynes with methyleneaziridines via C–C bond cleavage

Supplementary files

Article information

Article type
Communication
Submitted
07 Feb 2013
Accepted
10 Apr 2013
First published
11 Apr 2013

Chem. Commun., 2013,49, 5073-5075

Nickel-catalyzed [3 + 2] cycloaddition of diynes with methyleneaziridines via C–C bond cleavage

B. Pan, C. Wang, D. Wang, F. Wu and B. Wan, Chem. Commun., 2013, 49, 5073 DOI: 10.1039/C3CC41061G

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