Issue 34, 2013
From the journal:

Chemical Communications

Model studies towards the challenging angularly-oxygenated core of several angucyclinones from an oxidative dearomatization strategy†

Silvia Vila-Gisbert,a   Antonio Urbano*a  and  M. Carmen Carreño*a  

* Corresponding authors

a Departamento de Química Orgánica (Módulo 01), Facultad de Ciencias, Universidad Autónoma de Madrid, c/ Francisco Tomás y Valiente 7, Cantoblanco, 28049-Madrid, Spain
E-mail: antonio.urbano@uam.es, carmen.carrenno@uam.es

Abstract

Up to six differently substituted highly challenging angularly-oxygenated tricyclic core models of natural angucyclinones were stereoselectively synthesized from a common p-quinol intermediate obtained from Oxone-mediated oxidative dearomatization of the corresponding tricyclic phenol.

Graphical abstract: Model studies towards the challenging angularly-oxygenated core of several angucyclinones from an oxidative dearomatization strategy

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Article information

DOI
https://doi.org/10.1039/C3CC41221K
Article type
Communication
Submitted
15 Feb 2013
Accepted
12 Mar 2013
First published
13 Mar 2013

Chem. Commun., 2013,49, 3561-3563

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Model studies towards the challenging angularly-oxygenated core of several angucyclinones from an oxidative dearomatization strategy

S. Vila-Gisbert, A. Urbano and M. C. Carreño, Chem. Commun., 2013, 49, 3561 DOI: 10.1039/C3CC41221K

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