Issue 40, 2013

Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(i)-catalyzed hydroamination of terminal alkynes with parent hydrazine

Abstract

An anti-Bredt N-heterocyclic carbene gold(I) chloride complex was synthesized by taking advantage of the reversible insertion of the free carbene into the NH bond of hexamethyldisilazane. This precatalyst promotes the parent hydrazine hydroamination of terminal alkynes at room temperature.

Graphical abstract: Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(i)-catalyzed hydroamination of terminal alkynes with parent hydrazine

Supplementary files

Article information

Article type
Communication
Submitted
19 Feb 2013
Accepted
22 Mar 2013
First published
26 Mar 2013

Chem. Commun., 2013,49, 4483-4485

Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine

M. J. López-Gómez, D. Martin and G. Bertrand, Chem. Commun., 2013, 49, 4483 DOI: 10.1039/C3CC41279B

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