Issue 38, 2013
From the journal:

Chemical Communications

From a supramolecular tetranitrile to a porous covalent triazine-based framework with high gas uptake capacities†‡

Asamanjoy Bhunia,a   Vera Vasylyevaa  and  Christoph Janiak*a  

* Corresponding authors

a Institut für Anorganische Chemie und Strukturchemie, Universität Düsseldorf, 40204 Düsseldorf, Germany
E-mail: janiak@uni-duesseldorf.de
Fax: +49-211-81-12287
Tel: +49-211-81-12286

Abstract

Transformation of tetra(4-cyanophenyl)ethylene under Lewis acidic (ZnCl2) conditions at 400 °C leads to the formation of a porous covalent triazine-based organic framework (CTF) with a high surface area (2235 m2 g−1), high CO2 and CH4 uptakes and the highest hydrogen uptake for a CTF material (1.86 wt% at 77 K, 1 bar).

Graphical abstract: From a supramolecular tetranitrile to a porous covalent triazine-based framework with high gas uptake capacities

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Article information

DOI
https://doi.org/10.1039/C3CC41382A
Article type
Communication
Submitted
22 Feb 2013
Accepted
26 Mar 2013
First published
26 Mar 2013

Chem. Commun., 2013,49, 3961-3963

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From a supramolecular tetranitrile to a porous covalent triazine-based framework with high gas uptake capacities

A. Bhunia, V. Vasylyeva and C. Janiak, Chem. Commun., 2013, 49, 3961 DOI: 10.1039/C3CC41382A

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