We report the first synthesis of bridged pillararenes. Meso-form pillar[6]arenes were diastereo-selectively formed by bridging units of a per-hydroxylated pillar[6]arene in an alternating up-and-down manner with dialkyldichlorosilanes.
![Graphical abstract: Diastereoselective synthesis of meso-pillar[6]arenes by bridging between hydroquinone units in an alternating up-and-down manner](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C3CC41592A&imageInfo.ImageIdentifier.Year=2013)
T. Ogoshi, K. Demachi, K. Masaki and T. Yamagishi, Chem. Commun., 2013, 49, 3952 DOI: 10.1039/C3CC41592A
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