Solvent-induced lone pair activity tuning and vapoluminescence in a Pt2Pb cluster

Jesús R. Berenguer; Elena Lalinde; Antonio Martín; M. Teresa Moreno; Santiago Ruiz; Sergio Sánchez; Hamid R. Shahsavari

doi:10.1039/C3CC41638K

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Solvent-induced lone pair activity tuning and vapoluminescence in a Pt₂Pb cluster†‡

Jesús R. Berenguer,^a Elena Lalinde,*^a Antonio Martín,^b M. Teresa Moreno,*^a Santiago Ruiz,^a Sergio Sánchez^a and Hamid R. Shahsavari^a

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* Corresponding authors

^a Departamento de Química-Centro de Síntesis Química de La Rioja, (CISQ), Universidad de La Rioja, Logroño, Spain
E-mail: elena.lalinde@unirioja.es, teresa.moreno@unirioja.es

^b Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea, Universidad de Zaragoza-C.S.I.C., 50009 Zaragoza, Spain

Abstract

We report a novel cluster, [{Pt(C₆F₅)(bzq)}₂Pb(Spy)₂] 1, that displays reversible vapoluminescence to specific organic vapours; this behaviour can be related to the stereochemical activity of the lone pair around the Pb^II in the ground state and to the distinct distortion of the coordination environment (1 and 1–solvent) upon photoexcitation.

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Article information

DOI: https://doi.org/10.1039/C3CC41638K
Article type: Communication
Submitted: 04 Mar 2013
Accepted: 11 Apr 2013
First published: 11 Apr 2013

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Chem. Commun., 2013,49, 5067-5069

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Solvent-induced lone pair activity tuning and vapoluminescence in a Pt₂Pb cluster

J. R. Berenguer, E. Lalinde, A. Martín, M. Teresa Moreno, S. Ruiz, S. Sánchez and H. R. Shahsavari, Chem. Commun., 2013, 49, 5067 DOI: 10.1039/C3CC41638K

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Chemical Communications