Issue 50, 2013
From the journal:

Chemical Communications

C–F bond formation with fluoride anions – highly selective iodofluorination of simple allenes†

Can Xue,a   Xinpeng Jiang,a   Chunling Fu*a  and  Shengming Ma*a  

* Corresponding authors

a Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, People's Republic of China
E-mail: masm@sioc.ac.cn
Fax: +86-21-626-09305
Tel: +86-21-622-37360

Abstract

A highly regioselective (up to 99 : 1) iodofluorination reaction of simple allenes occurs under mild conditions with Et3N·3HF or Py·9HF to afford 2-iodoalken-3-yl fluorides.

Graphical abstract: C–F bond formation with fluoride anions – highly selective iodofluorination of simple allenes

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Article information

DOI
https://doi.org/10.1039/C3CC42014K
Article type
Communication
Submitted
19 Mar 2013
Accepted
22 Apr 2013
First published
24 Apr 2013

Chem. Commun., 2013,49, 5651-5653

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C–F bond formation with fluoride anions – highly selective iodofluorination of simple allenes

C. Xue, X. Jiang, C. Fu and S. Ma, Chem. Commun., 2013, 49, 5651 DOI: 10.1039/C3CC42014K

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