Issue 49, 2013
From the journal:

Chemical Communications

Monitoring the on–off switching of the electronic communication in diethynylplatinum(ii)-bridged dyads using triplet energy transfer†

Ahmed M. Soliman,a   Mohammed Abdelhameed,a   Eli Zysman-Colman*a  and  Pierre D. Harvey*a  

* Corresponding authors

a Département de Chimie, Université de Sherbrooke, 2550 Boulevard de l'Université, Sherbrooke, Québec, Canada J1K 2R1
E-mail: Pierre.Harvey@USherbrooke.ca
Fax: +1-819-821-8017
Tel: +1-819-821-7092

Abstract

Despite conjugation and downhill manifolds in [Ir]–[Pt]–[ZnTPP] ([ZnTPP] = (tetraphenylporphyrin)zinc(II), [Ir] = bis(phenylpyridinato)(bipyridine)iridium(III), [Pt] = trans-C[triple bond, length as m-dash]CPt(PBu3)2-C[triple bond, length as m-dash]C), essentially no T1[Ir] → S1/T1[ZnTTP] energy transfer occurs.

Graphical abstract: Monitoring the on–off switching of the electronic communication in diethynylplatinum(ii)-bridged dyads using triplet energy transfer

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Article information

DOI
https://doi.org/10.1039/C3CC42634C
Article type
Communication
Submitted
11 Apr 2013
Accepted
26 Apr 2013
First published
29 Apr 2013

Chem. Commun., 2013,49, 5544-5546

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Monitoring the on–off switching of the electronic communication in diethynylplatinum(II)-bridged dyads using triplet energy transfer

A. M. Soliman, M. Abdelhameed, E. Zysman-Colman and P. D. Harvey, Chem. Commun., 2013, 49, 5544 DOI: 10.1039/C3CC42634C

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