Issue 53, 2013
From the journal:

Chemical Communications

Thiourea-phosphonium salts from amino acids: cooperative phase-transfer catalysts in the enantioselective aza-Henry reaction†

Dongdong Cao,a   Zhuo Chai,b   Jiaxing Zhang,b   Zhengqing Ye,b   Hua Xiao,a   Hongyu Wang,a   Jinhao Chen,b   Xiaoyu Wua  and  Gang Zhao*ab  

* Corresponding authors

a Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China
E-mail: zhaog@mail.sioc.ac.cn

b Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China

Abstract

New chiral bifunctional thiourea-phosphonium salts have been developed based on natural amino acids as highly efficient phase-transfer catalysts in the enantioselective aza-Henry reaction.

Graphical abstract: Thiourea-phosphonium salts from amino acids: cooperative phase-transfer catalysts in the enantioselective aza-Henry reaction

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Article information

DOI
https://doi.org/10.1039/C3CC42864H
Article type
Communication
Submitted
18 Apr 2013
Accepted
13 May 2013
First published
14 May 2013

Chem. Commun., 2013,49, 5972-5974

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Thiourea-phosphonium salts from amino acids: cooperative phase-transfer catalysts in the enantioselective aza-Henry reaction

D. Cao, Z. Chai, J. Zhang, Z. Ye, H. Xiao, H. Wang, J. Chen, X. Wu and G. Zhao, Chem. Commun., 2013, 49, 5972 DOI: 10.1039/C3CC42864H

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