Issue 50, 2013
From the journal:

Chemical Communications

Simple and efficient synthesis of [MCI(NHC)] (M = Au, Ag) complexes†

Renso Visbal,a   Antonio Lagunaa  and  M. Concepción Gimeno*a  

* Corresponding authors

a Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC- Universidad de Zaragoza, 50009 Zaragoza, Spain
E-mail: gimeno@unizar.es
Fax: +34 976761187
Tel: +34 976762291

Abstract

A facile and efficient synthetic route leading to catalytically relevant N-heterocyclic carbene (NHC) gold complexes is described. The method consists of one pot synthesis starting from readily available imidazolium salts and [AuCl(tht)], in the presence of K2CO3. Using the same protocol NHC silver complexes have been synthesised starting from AgNO3.

Graphical abstract: Simple and efficient synthesis of [MCI(NHC)] (M = Au, Ag) complexes

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Article information

DOI
https://doi.org/10.1039/C3CC42919A
Article type
Communication
Submitted
19 Apr 2013
Accepted
06 May 2013
First published
07 May 2013

Chem. Commun., 2013,49, 5642-5644

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Simple and efficient synthesis of [MCI(NHC)] (M = Au, Ag) complexes

R. Visbal, A. Laguna and M. C. Gimeno, Chem. Commun., 2013, 49, 5642 DOI: 10.1039/C3CC42919A

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