Flexibility of ZIF-8 materials studied using 129Xe NMR

Marie-Anne Springuel-Huet; Andrei Nossov; Flavien Guenneau; Antoine Gédéon

doi:10.1039/C3CC43119C

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Flexibility of ZIF-8 materials studied using ¹²⁹Xe NMR†

Marie-Anne Springuel-Huet,*^a Andrei Nossov,^a Flavien Guenneau^a and Antoine Gédéon^a

Author affiliations

* Corresponding authors

^a UPMC Uni Paris 06, Collège de France and CNRS, UMR 7574, Laboratoire de Chimie de la Matière Condensée, case 196, 4 place Jussieu, 75252 Paris Cedex 05, France
E-mail: marie-anne.springuel-huet@upmc.fr
Tel: +33 144275537

Abstract

Structural changes in a porous hybrid inorganic–organic ZIF-8 compound have been explored using hyperpolarized ¹²⁹Xe NMR of adsorbed xenon at various temperatures. Upon xenon adsorption at low temperature, the organic linkers undergo a reorientation leading to a stepwise increase in xenon adsorption and in chemical shift.

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Article information

DOI: https://doi.org/10.1039/C3CC43119C
Article type: Communication
Submitted: 26 Apr 2013
Accepted: 18 Jun 2013
First published: 19 Jun 2013

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Chem. Commun., 2013,49, 7403-7405

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Flexibility of ZIF-8 materials studied using ¹²⁹Xe NMR

M. Springuel-Huet, A. Nossov, F. Guenneau and A. Gédéon, Chem. Commun., 2013, 49, 7403 DOI: 10.1039/C3CC43119C

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Chemical Communications