Issue 62, 2013
From the journal:

Chemical Communications

Asymmetric Ti-crossed Claisen condensation: application to concise asymmetric total synthesis of alternaric acid†‡

Ryohei Nagase,a   Yumiko Oguni,a   Satoko Ureshino,a   Hiroaki Mura,a   Tomonori Misaki*b  and  Yoo Tanabe*a  

* Corresponding authors

a Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo, Japan
E-mail: tanabe@kwansei.ac.jp
Fax: +81-79-565-9077
Tel: +81-79-565-8394

b Graduate School of Material Science, University of Hyogo, 3-2-1, Kohto, Kamigori, Hyogo 678-1297, Japan

Abstract

Asymmetric Ti-crossed Claisen condensation utilizing the dioxane-2,5-dione chiral template and its successful application to total synthesis of chiral alternaric acid are described.

Graphical abstract: Asymmetric Ti-crossed Claisen condensation: application to concise asymmetric total synthesis of alternaric acid

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Article information

DOI
https://doi.org/10.1039/C3CC43180K
Article type
Communication
Submitted
30 Apr 2013
Accepted
12 Jun 2013
First published
12 Jun 2013

Chem. Commun., 2013,49, 7001-7003

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Asymmetric Ti-crossed Claisen condensation: application to concise asymmetric total synthesis of alternaric acid

R. Nagase, Y. Oguni, S. Ureshino, H. Mura, T. Misaki and Y. Tanabe, Chem. Commun., 2013, 49, 7001 DOI: 10.1039/C3CC43180K

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