Issue 61, 2013
From the journal:

Chemical Communications

Dynamic control of dendrimer–fullerene association by axial coordination to the core†

Ken Albrecht,a   Yuto Kasai,a   Yasunori Kuramotoa  and  Kimihisa Yamamoto*a  

* Corresponding authors

a Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta Midori-ku, Yokohama 226-8503, Japan
E-mail: yamamoto@res.titech.ac.jp
Fax: +81-45-924-5260
Tel: +81-45-924-5260

Abstract

The effect of axial coordination of pyridine derivatives to the core porphyrin on the fullerene encapsulation of the 4th generation carbazole–phenylazomethine dendrimer (ZnPG2-2) was investigated. The axial coordination of large (bulky) pyridine derivatives affects the cavity in an allosteric manner, and the size-selectivity of the fullerene association could be controlled.

Graphical abstract: Dynamic control of dendrimer–fullerene association by axial coordination to the core

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Article information

DOI
https://doi.org/10.1039/C3CC43249A
Article type
Communication
Submitted
02 May 2013
Accepted
07 Jun 2013
First published
07 Jun 2013

Chem. Commun., 2013,49, 6861-6863

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Dynamic control of dendrimer–fullerene association by axial coordination to the core

K. Albrecht, Y. Kasai, Y. Kuramoto and K. Yamamoto, Chem. Commun., 2013, 49, 6861 DOI: 10.1039/C3CC43249A

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