Issue 64, 2013
From the journal:

Chemical Communications

Positive homotropic allosteric binding of silver(i) ions in multidentate azacalixpyridine macrocycles: effect on the formation and stabilization of silver nanoparticles†

Xin He,a   Xiao-Bin Xu,a   Xun Wanga  and  Liang Zhao*a  

* Corresponding authors

a Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (MOE), Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: zhaolchem@mail.tsinghua.edu.cn

Abstract

We report herein the occurrence of a positive homotropic allosteric binding effect of two macrocyclic azacalixpyridines. This effect was firstly found to be crucial in the formation and stabilization of ultra-small silver nanoparticles.

Graphical abstract: Positive homotropic allosteric binding of silver(i) ions in multidentate azacalixpyridine macrocycles: effect on the formation and stabilization of silver nanoparticles

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Article information

DOI
https://doi.org/10.1039/C3CC43415J
Article type
Communication
Submitted
08 May 2013
Accepted
17 Jun 2013
First published
17 Jun 2013

Chem. Commun., 2013,49, 7153-7155

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Positive homotropic allosteric binding of silver(I) ions in multidentate azacalixpyridine macrocycles: effect on the formation and stabilization of silver nanoparticles

X. He, X. Xu, X. Wang and L. Zhao, Chem. Commun., 2013, 49, 7153 DOI: 10.1039/C3CC43415J

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