Issue 54, 2013
From the journal:

Chemical Communications

Alkyl group versus hydrogen atom transfer from metal alkyls to macrocyclic rhodium complexes†

Jack M. Carrahera  and  Andreja Bakac*a  

* Corresponding authors

a Ames Laboratory and Chemistry Department, Iowa State University, Ames, Iowa 50011, USA
E-mail: bakac@ameslab.gov, carraher@iastate.edu
Fax: +1 515-294-4709
Tel: +1 515-294-3544

Abstract

Macrocyclic rhodium(II) complexes LRh(H2O)2+ react with (dmgH)2(H2O)CoR and with (H2O)5CrR2+ by alkyl transfer for R = CH3 to generate L(H2O)RhCH32+. When R = C2H5, C3H7 or C4H9, the reaction takes place by hydrogen atom abstraction from the coordinated alkyl and produces L(H2O)RhH2+ and an α-olefin.

Graphical abstract: Alkyl group versus hydrogen atom transfer from metal alkyls to macrocyclic rhodium complexes

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Article information

DOI
https://doi.org/10.1039/C3CC43472A
Article type
Communication
Submitted
09 May 2013
Accepted
29 May 2013
First published
30 May 2013

Chem. Commun., 2013,49, 6099-6101

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Alkyl group versus hydrogen atom transfer from metal alkyls to macrocyclic rhodium complexes

J. M. Carraher and A. Bakac, Chem. Commun., 2013, 49, 6099 DOI: 10.1039/C3CC43472A

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