Issue 72, 2013
From the journal:

Chemical Communications

Facile synthesis of heterotrimetallic metal–string complex [NiCoRh(dpa)4Cl2] through direct metal replacement†

Ming-Chuan Cheng,ab   Chi-Lun Mai,c   Chen-Yu Yeh,c   Gene-Hsiang Leea  and  Shie-Ming Peng*ab  

* Corresponding authors

a Department of Chemistry, National Taiwan University, Taipei, Taiwan, ROC
E-mail: smpeng@ntu.edu.tw
Fax: +886-2-8369-3765

b Institute of Chemistry, Academia Sinica, Taipei, Taiwan, ROC

c Department of Chemistry, National Chung Hsing University, Taichung, Taiwan, ROC

Abstract

This communication provides a practical strategy for the synthesis of heterotrimetallic extended metal atom chains with supported dpa− ligands. The transformation of the CoCoRh to a NiCoRh trinuclear complex can be achieved by direct metallic replacement. Furthermore, the first (CoRh)4+ metal–metal bond is described here.

Graphical abstract: Facile synthesis of heterotrimetallic metal–string complex [NiCoRh(dpa)4Cl2] through direct metal replacement

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Article information

DOI
https://doi.org/10.1039/C3CC43909G
Article type
Communication
Submitted
24 May 2013
Accepted
09 Jul 2013
First published
30 Jul 2013

Chem. Commun., 2013,49, 7938-7940

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Facile synthesis of heterotrimetallic metal–string complex [NiCoRh(dpa)4Cl2] through direct metal replacement

M. Cheng, C. Mai, C. Yeh, G. Lee and S. Peng, Chem. Commun., 2013, 49, 7938 DOI: 10.1039/C3CC43909G

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