Issue 79, 2013
From the journal:

Chemical Communications

Nitrous oxide reduction-coupled alkene–alkene coupling catalysed by metalloporphyrins†

Shunsuke Saito,a   Hiro Ohtake,b   Naoki Umezawa,a   Yuko Kobayashi,a   Nobuki Kato,a   Masaaki Hirobeb  and  Tsunehiko Higuchi*a  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya 467-8603, Japan
E-mail: higuchi@phar.nagoya-cu.ac.jp
Fax: +81 52 836 3435
Tel: +81 52 836 3435

b Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

Abstract

Porphyrin complexes of iron, manganese and cobalt catalysed reductive dimerization of alkenes with NaBH4 under N2O. The reaction system using FeIII porphyrin generated an FeI porphyrin intermediate that reduced N2O to regenerate FeIII porphyrin.

Graphical abstract: Nitrous oxide reduction-coupled alkene–alkene coupling catalysed by metalloporphyrins

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Article information

DOI
https://doi.org/10.1039/C3CC43912G
Article type
Communication
Submitted
24 May 2013
Accepted
04 Aug 2013
First published
05 Aug 2013

Chem. Commun., 2013,49, 8979-8981

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Nitrous oxide reduction-coupled alkene–alkene coupling catalysed by metalloporphyrins

S. Saito, H. Ohtake, N. Umezawa, Y. Kobayashi, N. Kato, M. Hirobe and T. Higuchi, Chem. Commun., 2013, 49, 8979 DOI: 10.1039/C3CC43912G

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