Issue 72, 2013
From the journal:

Chemical Communications

A Lewis acid catalytic core sandwiched by inorganic polyoxoanion caps: selective H2O2-based oxidations with [AlIII4(H2O)10(β-XW9O33H)2]6− (X = AsIII, SbIII)†

Mauro Carraro,*a   Bassem S. Bassil,*b   Antonio Sorarù,a   Serena Berardi,a   Andreas Suchopar,b   Ulrich Kortz*b  and  Marcella Bonchio*a  

* Corresponding authors

a ITM-CNR and Department of Chemical Sciences, University of Padova, via Marzolo 1, 35131 Padova, Italy
E-mail: mauro.carraro@unipd.it, marcella.bonchio@unipd.it
Fax: +39 0498275239

b School of Engineering and Science, Jacobs University, P.O. Box 750 561, 28725 Bremen, Germany
E-mail: b.bassil@jacobs-university.de, u.kortz@jacobs-university.de
Fax: +49 421-200-3229

Abstract

The AlIII-containing polyanions [AlIII4(H2O)10(β-XW9O33H)2]4− with X = AsIII (1) and SbIII (2) feature four aluminum(III) centers sandwiched by two trivacant (β-XW9O33) Keggin units, and trigger peroxide catalysis as well as substrate coordination via multiple Lewis acid site interactions.

Graphical abstract: A Lewis acid catalytic core sandwiched by inorganic polyoxoanion caps: selective H2O2-based oxidations with [AlIII4(H2O)10(β-XW9O33H)2]6− (X = AsIII, SbIII)

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Article information

DOI
https://doi.org/10.1039/C3CC44077J
Article type
Communication
Submitted
30 May 2013
Accepted
27 Jun 2013
First published
28 Jun 2013

Chem. Commun., 2013,49, 7914-7916

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A Lewis acid catalytic core sandwiched by inorganic polyoxoanion caps: selective H2O2-based oxidations with [AlIII4(H2O)10(β-XW9O33H)2]6− (X = AsIII, SbIII)

M. Carraro, B. S. Bassil, A. Sorarù, S. Berardi, A. Suchopar, U. Kortz and M. Bonchio, Chem. Commun., 2013, 49, 7914 DOI: 10.1039/C3CC44077J

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