Issue 71, 2013
From the journal:

Chemical Communications

Formation and stability of 3–5 atom gold clusters from gold complexes during the catalytic reaction: dependence on ligands and counteranions†

Judit Oliver-Meseguer,a   Antonio Leyva-Pérez,*a   Saud I. Al-Resayesb  and  Avelino Corma*a  

* Corresponding authors

a Instituto de Tecnología Química, Universidad Politécnica de Valencia, Consejo Superior de Investigaciones Científicas, Avenida de los Naranjos s/n, 46022 Valencia, Spain
E-mail: acorma@itq.upv.es, anleyva@itq.upv.es
Fax: +34963877809
Tel: +34963877800

b Chemistry Department, College of Science, King Saud University, B.O. BOX. 2455, Riyadh 11451, Saudi Arabia

Abstract

Gold complexes and salts decompose to catalytically active 3–5 atom gold clusters during the one-pot acylation–hydration of propargyl alcohols. Kinetic and spectroscopic studies show that released ligands and counteranions exert a direct effect on the formation and stability of the clusters.

Graphical abstract: Formation and stability of 3–5 atom gold clusters from gold complexes during the catalytic reaction: dependence on ligands and counteranions

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Article information

DOI
https://doi.org/10.1039/C3CC44104K
Article type
Communication
Submitted
31 May 2013
Accepted
03 Jul 2013
First published
04 Jul 2013

Chem. Commun., 2013,49, 7782-7784

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Formation and stability of 3–5 atom gold clusters from gold complexes during the catalytic reaction: dependence on ligands and counteranions

J. Oliver-Meseguer, A. Leyva-Pérez, S. I. Al-Resayes and A. Corma, Chem. Commun., 2013, 49, 7782 DOI: 10.1039/C3CC44104K

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