Issue 86, 2013
From the journal:

Chemical Communications

Encapsulation of supported metal nanoparticles with an ultra-thin porous shell for size-selective reactions

Zeyu Shang,†a   Rajankumar L. Patel,†a   Brian W. Evankoa  and  Xinhua Liang*a  

* Corresponding authors

a Department of Chemical and Biochemical Engineering, Missouri University of Science and Technology, Rolla, Missouri 65409, USA
E-mail: liangxin@mst.edu
Tel: +1-573-341-7632

Abstract

A novel nanostructured catalyst with an ultra-thin porous shell obtained from the thermal decomposition of an aluminium alkoxide film deposited by molecular layer deposition for size-selective reactions was developed. The molecular sieving capability of the porous metal oxide films was verified by examining the liquid-phase hydrogenation of n-hexene versus cis-cyclooctene.

Graphical abstract: Encapsulation of supported metal nanoparticles with an ultra-thin porous shell for size-selective reactions

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Article information

DOI
https://doi.org/10.1039/C3CC44208J
Article type
Communication
Submitted
04 Jun 2013
Accepted
29 Jul 2013
First published
31 Jul 2013

Chem. Commun., 2013,49, 10067-10069

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Encapsulation of supported metal nanoparticles with an ultra-thin porous shell for size-selective reactions

Z. Shang, R. L. Patel, B. W. Evanko and X. Liang, Chem. Commun., 2013, 49, 10067 DOI: 10.1039/C3CC44208J

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