Issue 72, 2013
From the journal:

Chemical Communications

The first structural confirmation of a C102fullerene as C102Cl20 containing a non-IPR carbon cage†

Shangfeng Yang,*a   Tao Wei,a   Song Wang,a   Daria V. Ignat'eva,b   Erhard Kemnitz*c  and  Sergey I. Troyanov*b  

* Corresponding authors

a Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Materials for Energy Conversion & Department of Materials Science and Engineering, University of Science and Technology of China (USTC), Hefei 230026, China
E-mail: sfyang@ustc.edu.cn
Fax: +86 551 63601750

b Chemistry Department, Moscow State University, Leninskie Gory, 119991 Moscow, Russia
E-mail: stroyano@thermo.chem.msu.ru
Fax: +7 494 9391240

c Institute of Chemistry, Humboldt University of Berlin, Brook-Taylor-Str. 2, 12489 Berlin, Germany
E-mail: erhard.kemnitz@chemie.hu-berlin.de
Fax: +49 030 20937277

Abstract

The chlorination of a pristine C102 fullerene separated by HPLC from fullerene soot afforded crystals of C102Cl20 with a non-IPR (IPR = isolated pentagon rule) cage containing two pairs of fused pentagons; structural reconstruction of a two-step Stone–Wales rearrangement revealed the starting IPR isomer (no. 19) of C102.

Graphical abstract: The first structural confirmation of a C102 fullerene as C102Cl20 containing a non-IPR carbon cage

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Article information

DOI
https://doi.org/10.1039/C3CC44386H
Article type
Communication
Submitted
11 Jun 2013
Accepted
11 Jul 2013
First published
11 Jul 2013

Chem. Commun., 2013,49, 7944-7946

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The first structural confirmation of a C102 fullerene as C102Cl20 containing a non-IPR carbon cage

S. Yang, T. Wei, S. Wang, D. V. Ignat'eva, E. Kemnitz and S. I. Troyanov, Chem. Commun., 2013, 49, 7944 DOI: 10.1039/C3CC44386H

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