Partial hydrolysis of AlCl3 with Ca(OH)2 and the amino acid glycine enables the selective transformation of the Al13 Keggin structures, outlining the ε → δ → γ isomerization process. Through this, a new γ-Al13 Keggin structure was able to be isolated and characterized through 27Al NMR and single-crystal XRD.
S. E. Smart, J. Vaughn, I. Pappas and L. Pan, Chem. Commun., 2013, 49, 11352 DOI: 10.1039/C3CC44844D
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