In this study, we have managed to find the optimal ATRA system that can obtain the highest mono-adduct yields with the purpose of minimizing the chain growth of divinyl monomers. The most highly hyperbranched polymers have been synthesized by the homopolymerization of multi-vinyl monomers via ATRA reaction.
Y. Zheng, T. Zhao, B. Newland, J. Poly and W. Wang, Chem. Commun., 2013, 49, 10124 DOI: 10.1039/C3CC44898C
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