Issue 77, 2013
From the journal:

Chemical Communications

Highly diastereoselective synthesis of chiral aminophenolate zinc complexes and isoselective polymerization of rac-lactide†

Haobing Wanga  and  Haiyan Ma*a  

* Corresponding authors

a Shanghai Key Laboratory of Functional Materials Chemistry and Laboratory of Organometallic Chemistry, East China University of Science and Technology, 130 Meilong Road, Shanghai, P. R. China
E-mail: haiyanma@ecust.edu.cn
Fax: +86 21 64253519
Tel: +86 21 64253519

Abstract

An enantiopure zinc complex supported by an aminophenolate ligand with multiple stereogenic centers has been diastereoselectively synthesized via the variation of the ortho-substituent of a phenoxy moiety and the N-alkyl group of a chiral pyrrolidinyl ring in the ligand framework, which displays high isoselectivity in the polymerization of rac-lactide.

Graphical abstract: Highly diastereoselective synthesis of chiral aminophenolate zinc complexes and isoselective polymerization of rac-lactide

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Article information

DOI
https://doi.org/10.1039/C3CC44980G
Article type
Communication
Submitted
03 Jul 2013
Accepted
30 Jul 2013
First published
31 Jul 2013

Chem. Commun., 2013,49, 8686-8688

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Highly diastereoselective synthesis of chiral aminophenolate zinc complexes and isoselective polymerization of rac-lactide

H. Wang and H. Ma, Chem. Commun., 2013, 49, 8686 DOI: 10.1039/C3CC44980G

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