Issue 82, 2013
From the journal:

Chemical Communications

A new versatile class of hetero-tetra-metallic assemblies: highlighting single-molecule magnet behaviour†

Nathalie Bridonneau,a   Lise-Marie Chamoreau,a   Philippe P. Lainé,b   Wolfgang Wernsdorferc  and  Valérie Marvaud*a  

* Corresponding authors

a IPCM-CNRS-7201, UPMC-Univ Paris 6, cc 42, 4 place Jussieu, 75252 Paris Cedex 05, France
E-mail: valerie.marvaud@upmc.fr
Fax: +33 (0)1 44 27 38 41
Tel: +33 (0)1 44 27 32 77

b Univ Paris Diderot, Sorbonne Paris Cité, ITODYS, UMR CNRS 7086, 15 rue J-A de Baïf, Paris, France

c Institut Néel, CNRS, Nanosciences department, BP 166, 25 rue des Martyrs, 38042 Grenoble Cedex 9, France

Abstract

Hetero-tetra-metallic species based on hexanuclear assemblies [((valen)M1)Ln(OH2)2(μM2(CN)8)]22− (Ln = GdIII, TbIII; M1 = CuII, NiII and M2 = MoIV, WIV) and co-crystallized mononuclear complexes [M3(tpy)2]2+ (M3 = NiII, RuII, OsII) were identified, fully characterized, and shown to constitute a new class of single-molecule magnets.

Graphical abstract: A new versatile class of hetero-tetra-metallic assemblies: highlighting single-molecule magnet behaviour

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Article information

DOI
https://doi.org/10.1039/C3CC45037F
Article type
Communication
Submitted
05 Jul 2013
Accepted
16 Aug 2013
First published
16 Aug 2013

Chem. Commun., 2013,49, 9476-9478

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A new versatile class of hetero-tetra-metallic assemblies: highlighting single-molecule magnet behaviour

N. Bridonneau, L. Chamoreau, P. P. Lainé, W. Wernsdorfer and V. Marvaud, Chem. Commun., 2013, 49, 9476 DOI: 10.1039/C3CC45037F

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