Issue 79, 2013
From the journal:

Chemical Communications

Self-assembly cavitand precisely recognizing hexafluorosilicate: a concerted action of two coordination and twelve CH⋯F bonds†

Anna S. Degtyarenko,a   Eduard B. Rusanov,b   Antonio Bauzá,c   Antonio Frontera,c   Harald Krautscheid,d   Alexander N. Chernega,b   Andriy A. Mokhire  and  Konstantin V. Domasevitch*a  

* Corresponding authors

a Inorganic Chemistry Dpt, Taras Shevchenko National University of Kyiv, Volodymyrska Str. 64/13, Kyiv 01601, Ukraine
E-mail: dk@univ.kiev.ua

b Institute of Organic Chemistry, Murmanska Str.4, Kyiv 253660, Ukraine

c Departament de Quimica, Universitat de les Illes Balears, 07122 Palma de Mallorca, Spain

d Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany

e Department of Chemie und Pharmazie, Universität Erlangen, Henkestr. 42, 91054 Erlangen, Germany

Abstract

Bis-pyridazine tectons support the structure of metallosupramolecular cavitand Cu2L44+, which is capable of selective encapsulation of SiF62− anions by a set of multiple host–guest interactions.

Graphical abstract: Self-assembly cavitand precisely recognizing hexafluorosilicate: a concerted action of two coordination and twelve CH⋯F bonds

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Article information

DOI
https://doi.org/10.1039/C3CC45271A
Article type
Communication
Submitted
12 Jul 2013
Accepted
05 Aug 2013
First published
07 Aug 2013

Chem. Commun., 2013,49, 9018-9020

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Self-assembly cavitand precisely recognizing hexafluorosilicate: a concerted action of two coordination and twelve CH⋯F bonds

A. S. Degtyarenko, E. B. Rusanov, A. Bauzá, A. Frontera, H. Krautscheid, A. N. Chernega, A. A. Mokhir and K. V. Domasevitch, Chem. Commun., 2013, 49, 9018 DOI: 10.1039/C3CC45271A

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