Issue 87, 2013

A new copper-based metal–organic framework as a promising heterogeneous catalyst for chemo- and regio-selective enamination of β-ketoesters

Abstract

Assembly of 5-nitro-1,2,3-benzenetricarboxylic acid (H3nbta) with CuII in the presence of 1,3-bis(1,2,4-triazol-1-yl)propane (1,3-btp) leads to a new metal–organic framework, [Cu(Hnbta)(1,3-btp)]·2H2O (A1), which is shown to be an efficient and recyclable heterogeneous catalyst for enamination of β-ketoesters with excellent product yields and selectivity.

Graphical abstract: A new copper-based metal–organic framework as a promising heterogeneous catalyst for chemo- and regio-selective enamination of β-ketoesters

Supplementary files

Article information

Article type
Communication
Submitted
14 Jul 2013
Accepted
31 Aug 2013
First published
02 Sep 2013

Chem. Commun., 2013,49, 10299-10301

A new copper-based metal–organic framework as a promising heterogeneous catalyst for chemo- and regio-selective enamination of β-ketoesters

Y. Zhao, D. Deng, L. Ma, B. Ji and L. Wang, Chem. Commun., 2013, 49, 10299 DOI: 10.1039/C3CC45310C

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