Issue 85, 2013
From the journal:

Chemical Communications

σ-Coordination of metal–boryl bonds to gold(i)†

Holger Braunschweig,*a   Krzysztof Radackia  and  Rong Shanga  

* Corresponding authors

a Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany
E-mail: h.braunschweig@mail.uni-wuerzburg.de
Fax: +49 931 31 84623
Tel: +49 931 31 85260

Abstract

The first examples of σ-coordinated metal–haloboryl complexes have been synthesised. The haloboryl moiety may be functionalized by nucleophilic substitution reactions, by which more electron-withdrawing substituents may be installed at the boron center.

Graphical abstract: σ-Coordination of metal–boryl bonds to gold(i)

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Article information

DOI
https://doi.org/10.1039/C3CC45455J
Article type
Communication
Submitted
18 Jul 2013
Accepted
15 Aug 2013
First published
15 Aug 2013

Chem. Commun., 2013,49, 9905-9907

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σ-Coordination of metal–boryl bonds to gold(I)

H. Braunschweig, K. Radacki and R. Shang, Chem. Commun., 2013, 49, 9905 DOI: 10.1039/C3CC45455J

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