Issue 82, 2013
From the journal:

Chemical Communications

High-pressure carbon dioxide uptake for porous organic cages: comparison of spectroscopic and manometric measurement techniques†

Tom Hasell,a   Jayne A. Armstrong,b   Kim E. Jelfs,a   Feng H. Tay,c   K. Mark Thomas,*b   Sergei G. Kazarian*c  and  Andrew I. Cooper*a  

* Corresponding authors

a University of Liverpool, Department of Chemistry and Centre for Materials Discovery, Liverpool L69 7ZD, UK
E-mail: aicooper@liverpool.com
Tel: +44 (0)151 794 3548

b Northern Carbon Research Laboratories, Bedson Building, Newcastle University, Newcastle upon Tyne, UK NE1 7RU
E-mail: mark.thomas@ncl.ac.uk
Tel: +44 (0)191 222 6839

c Department of Chemical Engineering and Chemical Technology, Imperial College of Science, Technology and Medicine, London, UK SW7 2BY
E-mail: s.kazarian@ic.ac.uk

Abstract

A chemoselective spectroscopic method for measuring CO2 sorption isotherms at pressures up to 14 MPa (140 bar) is validated against manometric measurements and molecular simulations, giving insights into the preferred sorption sites in various crystalline porous organic cages.

Graphical abstract: High-pressure carbon dioxide uptake for porous organic cages: comparison of spectroscopic and manometric measurement techniques

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Article information

DOI
https://doi.org/10.1039/C3CC45924A
Article type
Communication
Submitted
02 Aug 2013
Accepted
02 Sep 2013
First published
09 Sep 2013

Chem. Commun., 2013,49, 9410-9412

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High-pressure carbon dioxide uptake for porous organic cages: comparison of spectroscopic and manometric measurement techniques

T. Hasell, J. A. Armstrong, K. E. Jelfs, F. H. Tay, K. M. Thomas, S. G. Kazarian and A. I. Cooper, Chem. Commun., 2013, 49, 9410 DOI: 10.1039/C3CC45924A

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