Issue 84, 2013
From the journal:

Chemical Communications

Enantioselective ring-opening of meso-epoxides by aromatic amines catalyzed by a homochiral metal–organic framework†

Sridhar Regati,‡a   Yabing He,‡a   Muralidhara Thimmaiah,a   Peng Li,a   Shengchang Xiang,b   Banglin Chen*a  and  John Cong-Gui Zhao*a  

* Corresponding authors

a Department of Chemistry University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249, USA
E-mail: banglin.chen@utsa.edu, cong.zhao@utsa.edu
Fax: +1-210-458-7428

b College of Chemistry and Material, Fujian Normal University, 3 Shangsan Road, Cangshang Region, Fuzhou 350007, China

Abstract

The enantioselective ring-opening of meso-epoxides by aromatic amines was achieved by using a new chiral metal–organic framework UTSA-32a. The corresponding α-hydroxyamines were obtained with good yields and ee values (up to 89% ee).

Graphical abstract: Enantioselective ring-opening of meso-epoxides by aromatic amines catalyzed by a homochiral metal–organic framework

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Article information

DOI
https://doi.org/10.1039/C3CC45988H
Article type
Communication
Submitted
05 Aug 2013
Accepted
28 Aug 2013
First published
29 Aug 2013

Chem. Commun., 2013,49, 9836-9838

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Enantioselective ring-opening of meso-epoxides by aromatic amines catalyzed by a homochiral metal–organic framework

S. Regati, Y. He, M. Thimmaiah, P. Li, S. Xiang, B. Chen and J. C. Zhao, Chem. Commun., 2013, 49, 9836 DOI: 10.1039/C3CC45988H

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