Issue 84, 2013

Cubane and dicubane complexes stabilised by sterically demanding m-terphenyl ligands

Abstract

The reaction between sterically demanding m-terphenyl lithiate complexes and cadmium dihalides yields unusual cubanes where changes in ligand bulk afford different formulations, in particular a rare heterodicubane structure.

Graphical abstract: Cubane and dicubane complexes stabilised by sterically demanding m-terphenyl ligands

Supplementary files

Article information

Article type
Communication
Submitted
20 Aug 2013
Accepted
09 Sep 2013
First published
10 Sep 2013

Chem. Commun., 2013,49, 9752-9754

Cubane and dicubane complexes stabilised by sterically demanding m-terphenyl ligands

B. M. Gridley, T. J. Blundell, G. J. Moxey, W. Lewis, A. J. Blake and D. L. Kays, Chem. Commun., 2013, 49, 9752 DOI: 10.1039/C3CC46384B

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