An enantioselective [3+2] annulation of Morita–Baylis–Hillman carbonates with trifluoropyruvate catalyzed by modified cinchona alkaloids was developed in good to excellent yields with excellent diastereo- and enantioselectivities.
![Graphical abstract: Highly diastereo- and enantioselective [3+2] annulation of isatin-derived Morita–Baylis–Hillman carbonates with trifluoropyruvate catalyzed by tertiary amines](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C3CC46490C&imageInfo.ImageIdentifier.Year=2013)
N. Zhong, F. Wei, Q. Xuan, L. Liu, D. Wang and Y. Chen, Chem. Commun., 2013, 49, 11071 DOI: 10.1039/C3CC46490C
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