Issue 100, 2013

A flexible porous Cu(ii) bis-imidazolate framework with ultrahigh concentration of active sites for efficient and recyclable CO2 capture

Abstract

By virtue of planar Cu2(μ-OH)22+ cluster units, a flexible porous metal azolate framework not only adsorbs large amounts of CO2 (19.6 wt% or 266 g L−1 at 298 K and 1 atm) with a high zero-coverage adsorption enthalpy (−47 kJ mol−1), but also desorbs quickly at very low temperatures.

Graphical abstract: A flexible porous Cu(ii) bis-imidazolate framework with ultrahigh concentration of active sites for efficient and recyclable CO2 capture

Supplementary files

Article information

Article type
Communication
Submitted
28 Aug 2013
Accepted
07 Oct 2013
First published
07 Oct 2013

Chem. Commun., 2013,49, 11728-11730

A flexible porous Cu(II) bis-imidazolate framework with ultrahigh concentration of active sites for efficient and recyclable CO2 capture

D. Zhou, C. He, P. Liao, W. Xue, W. Zhang, H. Zhou, J. Zhang and X. Chen, Chem. Commun., 2013, 49, 11728 DOI: 10.1039/C3CC46597G

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