Issue 93, 2013
From the journal:

Chemical Communications

Room temperature switching of a neutral molecular iron(ii) complex†

Bernhard Schäfer,a   Cyril Rajnák,a   Ivan Šalitroš,ab   Olaf Fuhr,a   David Klar,c   Carolin Schmitz-Antoniak,c   Eugen Weschke,d   Heiko Wendec  and  Mario Ruben*ae  

* Corresponding authors

a Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Postfach 3640, 76021 Karlsruhe, Germany
E-mail: mario.ruben@kit.edu

b Institute of Inorganic Chemistry, Technology and Materials, Faculty of Chemical and Food Technology, Slovak University of Technology, Bratislava, Slovak Republic

c Faculty of Physics and Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, Lotharstraße 1, 47048 Duisburg, Germany

d Helmholtz-Zentrum Berlin für Materialien und Energie (HZB), Albert-Einstein-Str. 15, Berlin, Germany

e Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), CNRS-Université de Strasbourg, 23, rue du Loess, BP 43, Strasbourg cedex 2, France

Abstract

Abrupt room temperature switching (Tc = 295 K with a 5 K hysteresis) was achieved in a neutral FeII complex based on a 2-(1H-pyrazol-1-yl)-6-(1H-tetrazol-5-yl)pyridine ligand. Structural characterization and spin crossover study (via SQUID magnetometry, photoexcitation and X-ray absorption spectroscopy) in the solid state are described.

Graphical abstract: Room temperature switching of a neutral molecular iron(ii) complex

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Article information

DOI
https://doi.org/10.1039/C3CC46624H
Article type
Communication
Submitted
29 Aug 2013
Accepted
02 Oct 2013
First published
03 Oct 2013

Chem. Commun., 2013,49, 10986-10988

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Room temperature switching of a neutral molecular iron(II) complex

B. Schäfer, C. Rajnák, I. Šalitroš, O. Fuhr, D. Klar, C. Schmitz-Antoniak, E. Weschke, H. Wende and M. Ruben, Chem. Commun., 2013, 49, 10986 DOI: 10.1039/C3CC46624H

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