The first one-pot synthesis of a chiral pentakis-adduct of C60 utilising an opened-structure malonate tether

Charalambos P. Ioannou; Nikos Chronakis

doi:10.1039/C3CC46755D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

The first one-pot synthesis of a chiral pentakis-adduct of C₆₀ utilising an opened-structure malonate tether†

Charalambos P. Ioannou^a and Nikos Chronakis*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Cyprus, University str. 1, Building No 13, 2109 Aglantzia, Nicosia, Cyprus
E-mail: nchronak@ucy.ac.cy
Fax: +357 22895088
Tel: +357 22892781

Abstract

A pentakis-adduct of C₆₀ with an incomplete octahedral addition pattern was synthesised via a one-pot procedure using a tether equipped with five malonate moieties. The five-fold Bingel cyclopropanation of C₆₀ was completely regioselective and afforded a chiral, C₂-symmetric pentakis-adduct which was easily separated by column chromatography on SiO₂.

Download options Please wait...

Supplementary files

Supplementary information PDF (487K)

Article information

DOI: https://doi.org/10.1039/C3CC46755D
Article type: Communication
Submitted: 04 Sep 2013
Accepted: 25 Sep 2013
First published: 26 Sep 2013

Download Citation

Chem. Commun., 2013,49, 10611-10613

Permissions

Request permissions

The first one-pot synthesis of a chiral pentakis-adduct of C₆₀ utilising an opened-structure malonate tether

C. P. Ioannou and N. Chronakis, Chem. Commun., 2013, 49, 10611 DOI: 10.1039/C3CC46755D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications