Stoichiometry-controlled FeP nanoparticles synthesized from a single source precursor

Cornelia Hunger; Wilfried-Solo Ojo; Susanne Bauer; Shu Xu; Manfred Zabel; Bruno Chaudret; Lise-Marie Lacroix; Manfred Scheer; Céline Nayral; Fabien Delpech

doi:10.1039/C3CC46863A

Stoichiometry-controlled FeP nanoparticles synthesized from a single source precursor†

Cornelia Hunger,^a Wilfried-Solo Ojo,^b Susanne Bauer,^a Shu Xu,^b Manfred Zabel,^a Bruno Chaudret,^b Lise-Marie Lacroix,^b Manfred Scheer,*^a Céline Nayral*^b and Fabien Delpech*^b

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* Corresponding authors

^a Institut für Anorganische Chemie, Universität Regensburg, Regensburg D-93053, Germany
E-mail: manfred.scheer@chemie.uni-regensburg.de

^b Université de Toulouse; INSA, UPS, CNRS; LPCNO (Laboratoire de Physique et Chimie des Nano-Objets), 135 avenue de Rangueil, F-31077 Toulouse, France
E-mail: fabien.delpech@insa-toulouse.fr, celine.nayral@insa-toulouse.fr

Abstract

Phase-pure FeP nanoparticles (NPs) have been synthesized through low temperature thermolysis of the single source precursor [(CO)₄Fe(PH₃)]. Examination of the mechanism demonstrates the central role of the labile CO ligands and the weak P–H bonds to yield stoichiometry controlled FeP materials.

Chemical Communications

Stoichiometry-controlled FeP nanoparticles synthesized from a single source precursor†

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