Issue 99, 2013
From the journal:

Chemical Communications

Controlling helical chirality of cobalt complexes by chirality transfer from vicinal diamines†

Min-Seob Seo,ab   Kiseong Kimab  and  Hyunwoo Kim*ab  

* Corresponding authors

a Department of Chemistry, KAIST, Daejeon 305-701, Korea
E-mail: hwkim@kaist.edu

b Center for Nanomaterials and Chemical Reactions, Institute for Basic Science (IBS), Daejeon 305-701, Korea

Abstract

Stereoselective cis–trans isomerism of a CoIII–N2O2 complex has been achieved by coordinating chiral vicinal diamines. The induced metal-centered helical chirality can be exploited for chirality amplification and asymmetric coordination chemistry.

Graphical abstract: Controlling helical chirality of cobalt complexes by chirality transfer from vicinal diamines

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Article information

DOI
https://doi.org/10.1039/C3CC46887A
Article type
Communication
Submitted
09 Sep 2013
Accepted
03 Oct 2013
First published
16 Oct 2013

Chem. Commun., 2013,49, 11623-11625

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Controlling helical chirality of cobalt complexes by chirality transfer from vicinal diamines

M. Seo, K. Kim and H. Kim, Chem. Commun., 2013, 49, 11623 DOI: 10.1039/C3CC46887A

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